85544-38-3Relevant academic research and scientific papers
ZUR SYNTHESE VON ALKYLTHIO-, CYCLOALKYLTHIO- UND CYCLOALKYLDISULFIDEN DURCH OXIDATION VON MERCAPTOTHIOETHERN, BIS-MERCAPTO-THIOETHERN UND BIS-MERCAPTOALKANEN MIT JOD UND TRIETHYLAMIN
Weissflog, Eckhard
, p. 27 - 32 (2007/10/02)
The treatment of mercaptothioethers CH3(SCH2)nSH, n = 1,2 1,2 with equivalent amounts of iodine and triethyl amine leads to the formation of 2.4.5.7-tetrathiaoctane 3 and 2.4.6.7.9.11-hexathiadodecane 4.Oxidation of ethanedithiol-1.2 5 leads to polyethylene disulfide 6, 1.2.5.6-tetrathiacyclooctane 7 and 1.2.5.6.9.10.13.14-octathiacyclohexadecane 8, whereas bis-(mercaptomethyl)-sulfide 9 is converted to polymeric sulfides or disulfides and 1.2.4.6-tetrathiacycloheptane 10.
