855476-42-5Relevant academic research and scientific papers
Cyano-phosphorylation of aldehydes catalyzed by a nucleophilic N-heterocyclic carbene
Fukuda, Yoshimasa,Maeda, Yuka,Kondo, Kazuhiro,Aoyama, Toyohiko
, p. 397 - 398 (2007/10/03)
The first method for cyano-phosphorylation of aldehydes with diethyl cyanophosphonate in the presence of N-heterocyclic carbene prepared from 1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride and KOt-Bu, as a nucleophilic catalyst, is described.
CYANOPHOSPHATE: AN EFFICIENT INTERMEDIATE FOR CONVERSION OF CARBONYL COMPOUNDS TO NITRILES
Yoneda, Ryuji,Harusawa, Shinya,Kurihara, Takushi
, p. 3681 - 3684 (2007/10/02)
A novel and high yield conversion of saturated or unsaturated carbonyl compounds to nitriles via cyanophosphates by samarium diiodide in the presence of tert-butanol is described.
