85556-02-1

Upstream product

• 4335-90-4 3-benzylidene acetylacetone 
• 85545-64-8 3-(benzylidene)-2,4-bis-(trimethylsilyloxy)penta-1,4-diene 
• 922-67-8 propynoic acid methyl ester 
• 85545-67-1 5-Phenyl-4-trimethylsilanyloxy-5,8-dihydro-naphthalene-1,6-dicarboxylic acid dimethyl ester 

Relevant academic research and scientific papers

DIENE-TRANSMISSIVE DIELS-ALDER CYCLOADDITION REACTION OF BIS(SILYLOXY) CROSS-CONJUGATED TRIENES.

Multiple Diels-Alder reaction of bis(silyloxy) cross-conjugated trienes is presented. Two trienes, 3-benzylidene- and 3-(methoxymethylene)-2,4-bis(trimethylsilyloxy)-1,4-pentadiene, undergo two sequential Diels-Alder cycloadditions with a variety of dieno

3-BENZYLIDENE-2,4-BIS(TRIMETHYLSILYLOXY)-1,4-PENTADIENE; SYNTHESIS AND ITS DIENE-TRANSMISSIVE DIELS-ALDER REACTION

A novel cross-conjugated triene, 3-benzylidene-2,4-bis(trimethylsilyloxy)-1,4-pentadiene, was synthesized and the multiple Diels-Alder cycloaddition reactions to acetylenic dienophiles leading to the dihydronaphthols were demonstrated.