855658-52-5Relevant academic research and scientific papers
Rhodium-catalyzed arylative cyclization of alkynyl malonates by 1,4-rhodium(i) migration
Karad, Somnath Narayan,Lam, Hon Wai,Lewis, William,O'Brien, Luke
, p. 11366 - 11369 (2019)
The synthesis of functionalized 1-tetralones by the rhodium(i)-catalyzed reaction of alkynyl malonates with arylboronic acids is described. These arylative cyclizations proceed via an alkenyl-to-aryl 1,4-Rh(i) migration as a key step. Preliminary results
