855749-25-6

Basic information

• Product Name: 12-tosyl-12H-naphtho[1,2-b]carbazole
• Synonyms: 12-tosyl-12H-naphtho[1,2-b]carbazole
• CAS NO: 855749-25-6
• Molecular Weight: 421.519
• Mol File: 855749-25-6.mol

Chemical Properties

• CAS DataBase Reference: 12-tosyl-12H-naphtho[1,2-b]carbazole(CAS DataBase Reference)
• NIST Chemistry Reference: 12-tosyl-12H-naphtho[1,2-b]carbazole(855749-25-6)
• EPA Substance Registry System: 12-tosyl-12H-naphtho[1,2-b]carbazole(855749-25-6)

Safety Data

• Hazardous Substances Data: 855749-25-6(Hazardous Substances Data)

Upstream product

• 1137726-71-6 C₂₇H₂₅NO₄ 
• 98-59-9 p-toluenesulfonyl chloride 
• 1632137-99-5 C₃₄H₃₁NO₆S 
• 1632138-11-4 2-(3-(naphthalen-1-yl)prop-1-yn-1-yl) aniline 
• 1024669-94-0 2-(2-tri(isoprop-2-yl)silylethynyl)aniline 
• 1024669-96-2 C₂₄H₃₃NO₂SSi 
• 124643-39-6 2-naphthalen-2-ylethynylphenylamine 
• 615-43-0 2-iodophenylamine 
• 1024670-11-8 2-(2-(triisopropylsilyl)ethynyl)-N-(2-(naphthalen-1-yl)ethynyl)-N-tosylbenzenamine 
• 887925-07-7 N-ethynyl-4-methyl-N-{2-[(triisopropylsilanyl)-ethynyl]-phenyl}-benzenesulfonamide 
• 855749-02-9 4-methyl-N-(2-(naphthalen-2-ylethynyl)phenyl)benzenesulfonamide 
• 887925-10-2 N-(2-ethynylphenyl)-4-methyl-N-(naphthalen-1-ylethynyl)benzenesulfonamide 
• 855749-11-0 N-ethynyl-2-(2-(naphthalen-3-yl)ethynyl)-N-tosylbenzenamine 

Relevant articles and documents

Dual Gold-Catalyzed Formal Tetradehydro-Diels–Alder Reactions for the Synthesis of Carbazoles and Indolines

This work reports a dual gold-catalyzed tetradehydro-Diels–Alder reaction for the synthesis of nitrogen-containing aromatic heterocycles. Under the catalytic system (IPrAuNTf2/DIPEA), indolines and carbazoles as well as other N-containing aromatic heterocycles were prepared in high yields with good functional group tolerance. Unlike the traditional thermal tetradehydro-Diels–Alder reactions, diluted reaction concentration and radical prohibitors are not required for this protocol. Experimental data support a mechanism involving gold vinylidene species, which undergoes a 6 π electrocyclization, followed with 1,2-hydrogen shift.

Scandium-catalyzed intramolecular friedel-crafts reactions of 2-[(2-Alkyl-1 H -indol-3-yl)methylene]malonates

We have synthesized a variety of 2-[(2-alkyl-1H-indol-3-yl)methylene] malonates and studied their scandium-catalyzed intramolecular Friedel-Crafts reactions leading to the corresponding polycyclic compounds such as indeno[1,2-b]indoles and benzo[1,2-b]carbazoles. Georg Thieme Verlag Stuttgart New York.

Synthesis of carbazoles by dehydro Diels-Alder reactions of ynamides

A new approach to carbazoles and benzannulated carbazoles by means of intramolecular dehydro Diels-Alder of ynamides is reported. N-(o-Ethynyl)aryl ynamides and N-(o-ethynyl) arylynamides were prepared in a few steps starting from o-iodoaniline. Thermal c

Coupling and cycloaddition of ynamides: Homo- and Negishi coupling of tosylynamides and intramolecular [4 + 2] cycloaddition of N-(o-ethynyl)phenyl ynamides and arylynamides

N,N′-aryl- and N,N′-alkyl-buta-1,3-diyne-1,4-ditosylamides have been synthesized for the first time, in good to excellent yields, by copper-catalyzed dimerization of the corresponding N-aryl or N-alkyl tosylynamides. Negishi coupling of N-ethynylzinc tosy

Synthesis of carbazoles from ynamides by intramolecular dehydro Diels-Alder reactions

(Chemical Equation Presented) A new approach to carbazoles and benzannulated carbazoles by means of intramolecular dehydro Diels-Alder reactions of ynamides is reported. By using this approach, carbazoles and benzo[b]-, tetrahydrobenzo[b]-, naphtho[1,2-b]