85576-01-8Relevant academic research and scientific papers
Metal carbenoid mediated ring opening of furan-2-yloxy derivatives. Stereoselective synthesis of 2,4-hexadienedioic acid and 6-aryl-1-oxo-2,4-hexadienoic acid derivatives
Shieh, Po Chuen,Ong, Chi Wi
, p. 7303 - 7307 (2001)
2-Methoxy- and 2-trimethylsilyloxyfuran undergo facile ring opening reaction upon treatment with metal carbenoid. Treatment of 2-methoxyfuran with ethyl diazoacetate and aryl-α-diazocarbonyl compounds under metal catalysis afforded (2Z,4E)-hexadienedioate
Oxidation of Furans with Dimethyldioxirane. Interception of Malealdehyde and Related Aldehydes via Wittig Reactions
Adger, Brian J.,Barrett, Collette,Brennan, Joseph,McGuigan, Peter,McKervey, M. Anthony,Tarbit, Brian
, p. 1220 - 1222 (2007/10/02)
Unsaturated aldehydes including malealdehyde, generated in acetone by oxidation of furans with dimethyldioxirane, can be trapped efficiently by phosphoranes in Wittig reactions.
