855855-55-9

Basic information

• Product Name: (3aR,5S,6aR)-2,2-Dimethyl-5-((E)-styryl)-tetrahydro-furo[2,3-d][1,3]dioxole
• Synonyms: (3aR,5S,6aR)-2,2-Dimethyl-5-((E)-styryl)-tetrahydro-furo[2,3-d][1,3]dioxole
• CAS NO: 855855-55-9
• Molecular Weight: 246.306
• Mol File: 855855-55-9.mol

Chemical Properties

• CAS DataBase Reference: (3aR,5S,6aR)-2,2-Dimethyl-5-((E)-styryl)-tetrahydro-furo[2,3-d][1,3]dioxole(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,5S,6aR)-2,2-Dimethyl-5-((E)-styryl)-tetrahydro-furo[2,3-d][1,3]dioxole(855855-55-9)
• EPA Substance Registry System: (3aR,5S,6aR)-2,2-Dimethyl-5-((E)-styryl)-tetrahydro-furo[2,3-d][1,3]dioxole(855855-55-9)

Safety Data

• Hazardous Substances Data: 855855-55-9(Hazardous Substances Data)

Upstream product

• 4613-62-1 3-deoxy-1,2;5,6-di-O-isopropylidene-α-D-glucofuranoside 
• 4005-46-3 3-deoxy-1,2-O-isopropylidene-D-glucose 
• 4613-68-7 O¹,O²-isopropylidene-α-D-erythro-3-deoxy-pentodiald-1,4-ose 
• 1449-46-3 benzyltriphenylphosphonium bromide 

Downstream Products

• 855855-51-5 Benzoic acid (1S,3S,7R)-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-9-(4-methoxy-benzyloxy)-1-phenethyl-non-5-ynyl ester 
• 855855-59-3 (E)-(3S,5S,9R)-9-(tert-Butyl-dimethyl-silanyloxy)-11-(4-methoxy-benzyloxy)-1-phenyl-undec-7-ene-3,5-diol 
• 855855-61-7 tert-Butyl-{(E)-(R)-4-((4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane 
• 855855-63-9 (2Z,6E)-(R)-5-(tert-Butyl-dimethyl-silanyloxy)-8-((4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-octa-2,6-dienoic acid ethyl ester 
• 855855-62-8 (E)-(R)-3-(tert-Butyl-dimethyl-silanyloxy)-6-((4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-hex-4-en-1-ol 
• 855855-66-2 Benzoic acid (1S,3R)-3-hydroxy-1-phenethyl-4-(toluene-4-sulfonyloxy)-butyl ester 
• 855855-65-1 Benzoic acid (S)-1-((R)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-3-phenyl-propyl ester 
• 855855-58-2 Benzoic acid (1S,3R)-3,4-dihydroxy-1-phenethyl-butyl ester 
• 855855-57-1 (R)-1-((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-4-phenyl-butan-2-ol 
• 855855-52-6 Benzoic acid (S)-1-(R)-1-oxiranylmethyl-3-phenyl-propyl ester 
• 855855-64-0 (2S,3R,5R)-5-Phenethyl-tetrahydro-furan-2,3-diol 
• 855855-56-0 (2R,4R)-6-Phenyl-hexane-1,2,4-triol 
• 855855-54-8 (3aR,5R,6aR)-2,2-Dimethyl-5-phenethyl-tetrahydro-furo[2,3-d][1,3]dioxole 

Relevant articles and documents

A carbohydrate-based approach for the total synthesis of strictifolione

A chiral pool approach starting with D-glucose, using the Yamaguchi protocol and a Z-selective HWE reaction followed by lactonization, has been applied to execute the total synthesis of strictifolione.