855998-85-5Relevant academic research and scientific papers
β-Selective synthesis of 2′-deoxy-5,6-dihydro-4-thiouridine, a precursor of the unstable nucleoside product of ionising radiation damage 2′-deoxy-5,6-dihydrocytidine
Peyrane, Frederic,Clivio, Pascale
, p. 1685 - 1689 (2005)
4-Thio oxathiaphosphepane nucleosides 2-4 undergo a rearrangement in pyridine that leads selectively to the β anomer of the 2′-deoxy-5,6- dihydro-4-thiouridine derivative 5. This diastereoselective reaction proceeds through a multistep mechanism initiated
