856198-59-9

Basic information

• Product Name: (+/-)-Hydroxy-phenyl-(5.6.7.8-tetrahydro-naphthyl-⁽¹⁾)-methan
• CAS NO: 856198-59-9
• Molecular Weight: 238.329
• Mol File: 856198-59-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-Hydroxy-phenyl-(5.6.7.8-tetrahydro-naphthyl-⁽¹⁾)-methan(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-Hydroxy-phenyl-(5.6.7.8-tetrahydro-naphthyl-⁽¹⁾)-methan(856198-59-9)
• EPA Substance Registry System: (+/-)-Hydroxy-phenyl-(5.6.7.8-tetrahydro-naphthyl-⁽¹⁾)-methan(856198-59-9)

Safety Data

• Hazardous Substances Data: 856198-59-9(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 41828-13-1 5,6,7,8-tetrahydro-naphthalene-1-carbaldehyde 
• 555-31-7 aluminum isopropoxide 
• 74145-11-2 8-hydroxy-5,6,7,8-tetrahydronaphthalene-1-carboxylic acid 
• 41790-30-1 (5,6,7,8-tetrahydronaphthalene-1-yl)methanol 
• 4242-18-6 5,6,7,8-tetrahydro-1-naphthalenecarboxylic acid 

Downstream Products

• 35310-83-9 phenyl(5,6,7,8-tetrahydronaphthalen-1-yl)methanone 
• 6318-29-2 1,1,1,2-tetraphenyl-2-(5,6,7,8-tetrahydro-[1]naphthyl)-ethane 

Relevant articles and documents

Photochemically generated bicyclic ortho-quinodimethanes: Photo- enolization of bicyclic aldehydes and ketones

A photoenolization route to bicyclic ortho-quinodimethanes was investigated. Bicyclic photoenols were trapped in an intermolecular fashion with various dienophiles for the first time. All ortho-quinodimethane precursors were prepared via a selective route commencing with 1-indanol, α- tetralol and 1-benzosuberone. Irradiation afforded the E-photoenols exclusively which were trapped with equal efficiency except that derived from indane-4-carboxaldehyde. This low efficiency has been ascribed to rapid auto- oxidation of the aldehyde to carboxylic acid. The facial selectivity of the reaction between the photoenol from benzosuberan-9-carboxaldehyde and dimethyl fumarate was much lower when compared to the other aldehydes in this study. A distorted diene caused by the presence of the seven membered ring explains these results.