85620-51-5Relevant academic research and scientific papers
FLASH VACUUM PYROLYSIS OF 1-METHOXY-1,3-BIS(TRIMETHYLSILOXY)-1,3-DIENES : SYNTHESIS OF α-ALLENIC ACIDS.
Jullien, J.,Pechine, J.M.,Perez, F.,Piade, J.J.
, p. 4943 - 4944 (2007/10/02)
Flash vacuum pyrolysis at 680-700 deg C of 2-and 4- substituted 1-methoxy-1,3-bis(trimethylsiloxy)-1,3-butadienes yields α-allenic silyl esters which, upon hydrolysis, provide a direct route to α-allenic acids with good overall yield.
