856219-75-5Relevant academic research and scientific papers
Kinetic isotope effects in the thermal C2-C6 cyclization of enyne-allenes: Experimental evidence supports a stepwise mechanism
Schmittel, Michael,Vavilala, Chandrasekhar
, p. 4865 - 4868 (2007/10/03)
Kinetic isotope effects suggest that the thermal C2-C 6 cyclization of enyne-allenes proceeds through a stepwise diradical mechanism. This is even true if steric bulk at the alkyne terminus is large, contrary to theoretical predictio
