85632-68-4Relevant academic research and scientific papers
Inert Carbon Free Radicals. 7. "The (Kinetic) Reverse Effect" and Relevant Synthesis of New Monofunctionalized Triphenylmethyl Radicals and Their Nonradical Counterparts
Ballester, Manuel,Veciana, Jaime,Riera, Juan,Castaner, Juan,Rovira, Concepcion,Armet, Olga
, p. 2472 - 2480 (2007/10/02)
The high chemical passivity of the so-called "inert free radicals" (IFRs), particularly those derived from perchlorotriphenylmethyl (PTM), has allowed one to ascertain the kinetic influence of the free radical character on the reactivity of their nonradic
INFLUENCE OF A FREE RADICAL SUBSTITUENT ON REACTIVITY (REVERSE EFFECT). RESULTS INVOLVING BENZYLIC SYSTEMS
Ballester, M.,Veciana, J.,Riera, J.,Castaner, J.,Rovira, C.,Armet, O.
, p. 5075 - 5078 (2007/10/02)
The first examples of the influence of the free radical character on the reactivity of a non-radical substituent in the radical molecule (reverse effect) are reported.They include thermolysis, reductive dimerization and bromination, involving radicals rel
