85632-94-6Relevant academic research and scientific papers
Synthesis of cis-Olefins via Palladium-Catalyzed Coupling of Organic Halides, Norbornadiene, and Organotin Compounds
Kosugi, Masanori,Kimura, Tomoyuki,Oda, Hiroshi,Migita, Toshihiko
, p. 3522 - 3524 (2007/10/02)
Palladium-catalyzed cross-coupling of organic halides with organotin compounds in the presence of norbornadiene gave 5,6-disubstituted norbornene, which was treated by a retro Diels-Alder reaction yielding cis-ethene and cyclopentadiene.
ONE-POT PALLADIUM-CATALYZED SYNTHESIS OF 2,3-DISUBSTITUTED BICYCLOHEPTANES AND BICYCLOHEPT-5-ENES
Catellani, Marta,Chiusoli, Gian Paolo
, p. 4517 - 4520 (2007/10/02)
A new and highly stereoselective palladium-catalyzed synthesis is reported, based on two subsequent insertion of the bicycloheptene system into an aryl or vinylpalladium bond, formed in situ from aryl or vinyl bromides.
