856405-77-1 Usage
Reactions
Ligand used in the cobalt-catalyzed alkenylzincation of unfunctionalized alkynes.
Ligand used in the cobalt-catalyzed alkylboration of alkenes.
Ligand used in the palladium-catalyzed N-alkylation of amines using primary and secondary alcohols.
Ligand used in the palladium-catalyzed methylation of alkynyl C(sp)-H bonds with dimethyl sulfonium ylides
Check Digit Verification of cas no
The CAS Registry Mumber 856405-77-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,5,6,4,0 and 5 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 856405-77:
(8*8)+(7*5)+(6*6)+(5*4)+(4*0)+(3*5)+(2*7)+(1*7)=191
191 % 10 = 1
So 856405-77-1 is a valid CAS Registry Number.
InChI:InChI=1S/C31H48OP2/c1-27(2,3)33(28(4,5)6)23-19-15-17-21-25(23)32-26-22(31(21,13)14)18-16-20-24(26)34(29(7,8)9)30(10,11)12/h15-20H,1-14H3
856405-77-1Relevant academic research and scientific papers
Mispelaere-Canivet, Clotilde,Spindler, Jean-Francis,Perrio, Stéphane,Beslin, Pierre
, p. 5253 - 5259 (2005)
The cross-coupling of aliphatic and aromatic thiols and aryl bromides/triflates mediated by a Pd2(dba)3/Xantphos catalytic system in refluxing xylene (140°C) affords the corresponding aryl thioethers in good to excellent yields.