85647-65-0

Upstream product

• 16721-97-4 trityl perchlorate 
• 76235-19-3 1,2-O-<1-(exo-cyano)ethylidene>-6-deoxy-α-D-glucopyranose 
• 82769-42-4 1,2-O-<1-(exo-cyano)ethylidene>-β-L-rhamnopyranose 
• 69908-87-8 3,4-di-O-acetyl-1,2-O-<1-(exo-cyano)ethylidene>-β-L-rhamnopyranose 
• 69908-87-8 3,4-di-O-acetyl-1,2-O-<1-(exo-cyano)ethylidene>-6-deoxy-α-D-glucopyranose 

Downstream Products

• 85572-79-8 3-O-(2-O-acetyl-3,4-di-O-benzoyl-α-L-rhamnopyranosyl)-4-O-benzoyl-1,2-O-<1-(exo-cyano)ethylidene>-β-L-rhamnopyranose 
• 85572-80-1 4-O-benzoyl-3-O-trityl-1,2-O-<1-(exo-cyano)ethylidene>-β-L-rhamnopyranose 
• 113829-52-0 4-O-acetyl-3-O-trityl-1,2-O-<1-(exo-cyano)ethylidene>-β-L-rhamnopyranose 
• 76235-18-2 4-O-acetyl-1,2-O-<1-(exo-cyano)ethylidene>-6-deoxy-3-O-trityl-α-D-glucopyranose 

Relevant academic research and scientific papers

THE EFFECT OF HIGH PRESSURE ON THE STEREOSPECIFICITY OF THE GLYCOSYLATION REACTION

At a pressure of 1,4 GPa and room temperature, the glycosylation of trityl ethers by 1,2-O-cyanoethylidene derivatives of sugars, and the polycondensation of the proper monomers in dichloromethane, proceed with absolute stereospecificity, giving rise to a