85649-22-5

Upstream product

• 85624-95-9 c-4-t-butyl-t-1-prop-1'-ynylcyclohexan-r-1-ol 
• 85624-96-0 t-4-t-butyl-t-1-prop-1'-ynylcyclohexan-r-1-ol 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 42437-24-1 1-allyl 4-tert-butylcyclohexan-1-ol 

Relevant academic research and scientific papers

Stereoselective alkene isomerization over one position

Although controlling both the position of the double bond and E:Z selectivity in alkene isomerization is difficult, 1 is a very efficient catalyst for selective mono-isomerization of a variety of multifunctional alkenes to afford >99.5% E-products. Many reactions are complete within 10 min at room temperature. Even sensitive enols and enamides susceptible to further reaction can be generated. Catalyst loadings in the 0.01-0.1 mol% range can be employed. E-to-Z isomerization of the product from diallyl ether was only -6 times as fast as its formation, showing the extremely high kinetic selectivity of 1.

Reactions of Propargyl Alcohols. V. Lithium Aluminium Hydride Reduction of Some C1-Epimeric 4-t-Butyl-1-prop-1'-ynylcyclohexanols

The preparation and lithium aluminium hydride reductions of C1-epimeric 4-t-butyl-1-prop-1'-ynylcyclohexanols (8) and (9), and their 2-methyl (10) and (11) and 2,6-dimethyl (12) and (13) derivatives are described.The effects of solvent and substrate struc