856675-97-3

Upstream product

• 848617-93-6 (+/-)-B-methoxy-10-trimethylsilyl-9-borabicyclo[3.3.2]decane 
• 90-82-4 pseudoephedrine 

Downstream Products

• 856675-86-0 (S)-9-((S)-1-Phenyl-but-3-enyloxy)-10-trimethylsilanyl-9-bora-bicyclo[3.3.2]decane 
• 856676-11-4 (1R,2R)-N-methyl-1-phenyl-1-(((1S,5S,10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]decan-9-yl)oxy)propan-2-amine 

Relevant academic research and scientific papers

N-propargylamides via the asymmetric Michael addition of B-alkynyl-10-TMS-9-borabicyclo[3.3.2]decanes to N-acylimines

The asymmetric synthesis of N-propargylamides through Michael addition of the alkynylborane 1 to N-acylimines is reported. The N-acetylimines provide the best substrates for the process exhibiting high selectivity (56-95% ee) with predictable stereochemis