85669-50-7Relevant academic research and scientific papers
REACTIONS DE MICHAEL SUR DES AMIDES α,β INSATURES ACTIVEES PAR LE SYSTEME CsF/Si(OCH3)4
Chuit, C.,Corriu, R. J. P.,Perz, R.,Reye, C.
, p. 2293 - 2302 (1986)
Michael addition of compounds having acidic hydrogen (ketones, nitro derivatives, ethyl cyanoacetate and ethyl malonate) on α,β unsaturated amides are carried out in the presence of the system CsF/Si(OCH3)4.The reaction takes place in heterogeneous medium
1,4-ADDITION REACTION TO α,β UNSATURATED TERTIARY AMIDES
Chuit, C.,Corriu, R. J. P.,Reye, C.
, p. 5531 - 5534 (2007/10/02)
Ketones, phenylacetonitrile, ethylmalonate, cyanoethyl acetate, nitromethane and nitroethane were found to add directely to α,β-unsaturated tertiary amides in the presence of CsF/Si(OMe)4 to give 1,4-addition products in fair to good yields.
