85683-74-5Relevant academic research and scientific papers
Twofold unsymmetrical C-H functionalization of PyrDipSi-substituted arenes: A general method for the synthesis of substituted meta-halophenols
Sarkar, Dhruba,Melkonyan, Ferdinand S.,Gulevich, Anton V.,Gevorgyan, Vladimir
, p. 10800 - 10804 (2013/10/22)
And the world is your oyster Sequential halogenation/oxygenation reactions of 2-diisopropylsilylpyrimidine-substituted arenes provide a general and efficient synthesis of substituted meta-halophenols from simple aryl iodides (see scheme; Piv=pivaloyl). The products are poised to undergo diverse C-C, C-N, and C-O bond-forming reactions that enable the transformation of their framework and the introduction of valuable functionalities. Copyright
