Cas 856865-04-8,[Ir(P(C6H5)3)2(C6H5CCHC(CH3)O)(CH2C(O)C6H4NO)](1+)*SbF6(1-)=[Ir(P(C6H5)3)2(C6H5CCHC(CH3)O)(CH2C(O)C6H4NO)]SbF6

856865-04-8

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Product Name: [Ir(P(C₆H₅)3)2(C₆H₅CCHC(CH₃)O)(CH₂C(O)C₆H₄NO)]⁽¹⁺⁾*SbF₆^(1-)=[Ir(P(C₆H₅)3)2(C₆H₅CCHC(CH₃)O)(CH₂C(O)C₆H₄NO)]SbF₆
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CAS NO:856865-04-8
Molecular Formula:
Molecular Weight: 1245.86
EINECS: N/A
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Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: [Ir(P(C₆H₅)3)2(C₆H₅CCHC(CH₃)O)(CH₂C(O)C₆H₄NO)]⁽¹⁺⁾*SbF₆^(1-)=[Ir(P(C₆H₅)3)2(C₆H₅CCHC(CH₃)O)(CH₂C(O)C₆H₄NO)]SbF₆(CAS DataBase Reference)
NIST Chemistry Reference: [Ir(P(C₆H₅)3)2(C₆H₅CCHC(CH₃)O)(CH₂C(O)C₆H₄NO)]⁽¹⁺⁾*SbF₆^(1-)=[Ir(P(C₆H₅)3)2(C₆H₅CCHC(CH₃)O)(CH₂C(O)C₆H₄NO)]SbF₆(856865-04-8)
EPA Substance Registry System: [Ir(P(C₆H₅)3)2(C₆H₅CCHC(CH₃)O)(CH₂C(O)C₆H₄NO)]⁽¹⁺⁾*SbF₆^(1-)=[Ir(P(C₆H₅)3)2(C₆H₅CCHC(CH₃)O)(CH₂C(O)C₆H₄NO)]SbF₆(856865-04-8)

Safety Data

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Safety Statements: N/A
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RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 856865-04-8(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 856865-04-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,5,6,8,6 and 5 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 856865-04:
(8*8)+(7*5)+(6*6)+(5*8)+(4*6)+(3*5)+(2*0)+(1*4)=218
218 % 10 = 8
So 856865-04-8 is a valid CAS Registry Number.

856865-04-8Upstream product

856865-04-8Downstream Products

856865-04-8Relevant academic research and scientific papers

Intramolecular oxygen transfer from nitro groups to C≡C bonds mediated by iridium hydrides

Li, Xingwei,Incarvito, Christopher D.,Vogel, Tiffany,Crabtree, Robert H.

, p. 3066 - 3073 (2008/10/09)

The functionalized alkynes o-RC≡C(C6H4)NO 2 (R = H or alkyl) formally insert into two iridium hydrides, during which O-transfer of the nitro group into the C≡C bond of o-RC≡ C(C6H4)NO2 is observed. For the terminal alkyne with R = H, iridium(III) nitroso complexes were isolated. For internal alkynes with R = Me or nPr, iridium hydride anthranil complexes were obtained as a result of O-transfer with a different regiochemistry. Mechanisms for these transformations, including a previously unknown O-transfer step from the nitro to the RC≡C bond, are proposed.

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