857028-10-5Relevant academic research and scientific papers
Polymer-supported manganese porphyrin catalysts - Peptide-linker promoted chemoselectivity
Brule, Emilie,Hii, King Kuok,De Miguel, Yolanda R.
, p. 1971 - 1976 (2005)
Manganese porphyrin catalysts were tethered to polymer-supports via peptide linkers. The reactivity and chemoselectivity of the catalysts were assessed in the epoxidation of limonene. It was found that the inclusion of a peptide linker incorporating a donor heteroatom which could act as an axial ligand led to a supported manganese porphyrin catalyst with unprecedented selectivity and stability. The Royal Society of Chemistry 2005.
