85711-12-2Relevant academic research and scientific papers
Selective reduction of 2-(β-cyanoalkyl)oxazolines into cyclic amidines
Langlois,Dahuron
, p. 3993 - 3996 (1996)
The selective reduction of 2-(2-cyanopropyl)-4,5-dihydrooxazoles into heterocyclic amidines has been achieved with LAH in carefully controlled conditions. This reaction was applied to the enantioselective synthesis of (S)-4-methylpyrrolidin-2-one, starting from (R)-phenylglycinol derived oxazoline 1b.
Copper-Catalyzed Diastereoselective Addition of Diborylmethane to N-tert-Butanesulfinyl Aldimines: Synthesis of β-Aminoboronates
Park, Jinyoung,Lee, Yeosan,Kim, Junghoon,Cho, Seung Hwan
supporting information, p. 1210 - 1213 (2016/03/15)
We have developed a highly chemo- and diastereoselective alkylation of N-tert-butanesulfinyl aldimines with diborylmethane. Whereas the addition of diborylmethane under metal-free conditions shows poor diastereoselectivity, the use of a copper catalyst an
Pheromones, 67. - Synthesis of the Enantiomers of (Z)-14-Methyl-8-hexadecenal , the Pheromone of Some Trogoderma Species (Coleoptera: Dermestidae)
Bestmann, Hans Juergen,Frighetto, Rosa T. S.,Frighetto, Nelson,Vostrowsky, Otto
, p. 877 - 880 (2007/10/02)
The separation of diastereomeric phenylglycinolamides of 2-methylbutyric acid by means of MPLC yields the pure enantiomers of the acid, from which (R,Z)- and (S,Z)-14-methyl-8-hexadecenal (1) (trogodermal) can be obtained.
