Cas 85718-76-9,(1R,2S,3R)-3-(2,2-dimethylpropoxy)-4,7,7-trimethylbicyclo<2.2.1>heptan-2-ol

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Check Digit Verification of cas no

The CAS Registry Mumber 85718-76-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,5,7,1 and 8 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 85718-76:
(7*8)+(6*5)+(5*7)+(4*1)+(3*8)+(2*7)+(1*6)=169
169 % 10 = 9
So 85718-76-9 is a valid CAS Registry Number.

85718-76-9Upstream product

89195-62-0 (S)-3,7-Dimethyl-oct-6-enoic acid (1R,2S,3R,4S)-3-(2,2-dimethyl-propoxy)-4,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester

85718-76-9Downstream Products

85718-76-9Relevant academic research and scientific papers

ASYMMETRIC 1,4-ADDITIONS OF COORDINATED MeCu.BF3 TO CHIRAL ENOATES: ENANTIOSELECTIVE SYNTHESES OF (S)-(-)-CITRONELLIC ACID

Oppolzer, Wolfgang,Moretti, Robert,Godel, Thierry,Meunier, Anne,Loeher, Heinz

, p. 4971 - 4974 (1983)

nBu3P- or cyanide-stabilized RCu.BF3 (R=Me, 4-Me-3-pentenyl) undergo efficient 1,4-additions to neopentylether-shielded trans-enoates.Thus chiral β-substituted carboxylic acids e.g. (S)-citronellic acid were obtained in high e.e. (Schemes 2 and 4).

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