85733-06-8

Upstream product

• 16883-61-7 trimethylsilyl isobutyrate 
• 141809-67-8 1-methyl-3-phenylpropyl trimethylsilyl ether 
• 2432-50-0 ethyl β-methylthiopropionate 
• 2344-70-9 1-phenyl-3-butanol 
• 79-30-1 isobutyryl chloride 
• 113761-32-3 4-phenyl-2-butyl 1-imidazolecarboxylate 
• 1068-55-9 isopropylmagnesium chloride 

Relevant academic research and scientific papers

Simple method for the preparation of esters from Grignard reagents and alkyl 1-imidazolecarboxylates

The reaction of Grignard reagents with alkyl imidazolecarboxylates, which were prepared from alcohols with carbonyl diimidazole, gave the corresponding esters in good to excellent yields. This method conveniently provides esters from alkyl halides and alcohols by C1-carbon chain extension.

A New and Efficient Esterification Reaction via Mixed Anhydrides by the Promotion of a Catalytic Amount of Lewis Acid

In the presence of a catalytic amount of Lewis acid, various carboxylic esters or S-phenyl carbothioates are prepared in excellent yields by the respective reactions of equimolar amounts of silyl carboxylates and alkyl silyl ethers or phenyl silyl sulfides with 4-trifluoromethylbenzoic anhydride.

An Efficient Method for the Preparation of Carboxylic Esters via Mixed Anhydrides by the Promotion of a Catalytic Amount of Lewis Acid

Various carboxylic esters are prepared in excellent yields by the reaction of nearly equimolar amounts of silyl derivatives of carboxylic acids and alcohols with p-trifluoromethylbenzoic anhydride in the presence of a catalytic amount of Lewis acid.

A Novel Transesterification of Thioesters with Alcohols by an Electrochemical Activation

Esters were synthesized from thioesters and alcohols in high yields by an electrochemical activation.Different results were obtained by the use of n-Bu4N+ I- and LiBF4 as the electrolyte.

FACILE METHOD FOR THE ACYLATION OF ALCOHOLS AND AMIDES BY THE USE OF 1,1'-DIMETHYLSTANNOCENE AND ACYL CHLORIDES

Acylation of alcohols and amides was effected under mild conditions by the use of 1,1'-dimethylstannocene and acyl chlorides, giving the corresponding esters and imides in good to excellent yields.