857490-18-7Relevant articles and documents
Method for producing amines by homogeneously catalyzed reductive amination of carbonyl compounds
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Page/Page column 13, (2010/02/11)
The invention relates to the preparation of chiral or achiral amines by reaction of aldehydes or ketones with ammonia or primary or secondary amines in the presence of hydrogen and in the presence of homogeneous metal catalysts under mild conditions. Metal catalysts which can be used are complexes of late transition metals with chiral or achiral phosphorus-containing ligands.
Diphenylboron Chelates of α-(Dialkylamino)carboxylic Acids and their N-Oxides
Kliegel, Wolfgang,Graumann, Juergen
, p. 950 - 961 (2007/10/02)
α-(Dialkylamino)carboxylic acids and their N-oxides react with oxybis(diphenylborane) or similar diphenylborane derivatives to give five- or six-membered diphenylboron chelate rings, respectively, the structure of which is supported by spectroscopic evidence.