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BENZOYL HYDRAZONE DERIVATIVES OF MONO(CYCLOPENTADIENYL)-TITANIUM(IV)CHLORIDE
Kher, S.,Kumari, V.,Kapoor, R. N.
, p. 333 - 340 (2007/10/02)
The reactions of mono(cyclopentadienyl)titanium(IV) chloride (CpTiCl3) with monobasic benzoyl hydrazones (BHyH) (molar ratios 1:1 and 1:2) and dibasic benzoyl hydrazones (BHy'H2) (molar ratio 1:1) have been carried out in refluxing dichloromethane.These reactions lead to the formation of the products of the type: CpTiCl2(BHy), CpTiCl(BHy)2 and CpTiCl(BHy').The compounds thus obtained have been characterized on the basis of elemental analysis, electrical conductance measurements and spectral (IR, NMR and electronic) data.
