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857769-21-2

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857769-21-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 857769-21-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,5,7,7,6 and 9 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 857769-21:
(8*8)+(7*5)+(6*7)+(5*7)+(4*6)+(3*9)+(2*2)+(1*1)=232
232 % 10 = 2
So 857769-21-2 is a valid CAS Registry Number.

857769-21-2Relevant academic research and scientific papers

Copper-catalyzed enantioselective inverse electron-demand hetero-diels-alder reactions of diazadienes with enol ethers: Efficient synthesis of chiral pyridazines

Gao, Shuang,Chen, Jia-Rong,Hu, Xiao-Qiang,Cheng, Hong-Gang,Lu, Liang-Qiu,Xiao, Wen-Jing

supporting information, p. 3539 - 3544 (2014/01/06)

A highly efficient and enantioselective inverse electron-demand hetero-Diels-Alder reaction of in situ generated 1,2-diaza-1,3-dienes with enol ethers has been developed with the use of a chiral copper/bisoxazoline complex as the catalyst. The reaction ex

Enantioselective synthesis of dihydropyrazoles by formal [4+1] cycloaddition of in situ-derived azoalkenes and sulfur ylides

Chen, Jia-Rong,Dong, Wan-Rong,Candy, Mathieu,Pan, Fang-Fang,Joerres, Manuel,Bolm, Carsten

supporting information; experimental part, p. 6924 - 6927 (2012/06/15)

An unprecedented strategy to access highly enantioenriched dihydropyrazoles is described. It involves formal [4+1] cycloadditions of in situ-derived azoalkenes and sulfur ylides catalyzed by a chiral copper/Tol-BINAP complex. A variety of synthetically and biologically important dihydropyrazoles have been obtained with high enantioselectivities (up to 97:3 er) in good yields (83-97%).

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