857793-19-2Relevant academic research and scientific papers
X-ray structural and nuclear magnetic resonance study of open chain and macrocyclic thioether complexes
Lucas, C. Robert,Liu, Shuang,Newlands, Michael J.,Gabe, Eric J.
, p. 1357 - 1363 (2007/10/02)
Preparations of the thiophenophane and open chain thioether complexes MX2*BBTE (M=Pd; X=Cl, I)(M=Pt; X=Cl) (BBTE=1,2-bis(benzylthio)ethane) and MX2*L (M=Pd; X=Cl, Br, I, SCN)(M=Pt; X=Cl)(L=2,5,8-trithia(2,5)thiophenophane) are described.The molecular structure of PdBr2*L which contains a weak thiophene-sulfur-to-palladium interaction has been determined: space group P21/n, a=8.3569(3), b=16.3254(15), c=11.1462(3) Angstroem, β=92.833(4) deg, Z=4, Rf=0.060, Rw=0.058.The electronic, low frequency ir, and 13C nmr spectra are described.Variable temperature 1H nmr spectra are discussed and it is concluded that the open chain complexes undergo rapid conformational exchange at room temperature but are configurationally rigid unless the temperature is increased.In contrast, the macrocyclic comlexes undergo very limited conformational and no configurational exchange up to their decomposition temperatures.They are also nonfluxional in the same temperature range.Chemical exchange of acidic ligand hydrogens and a metal-ligand dissociative equilibrium were also detected when X=SCN.
