857802-75-6Relevant academic research and scientific papers
2-[(Trimethylsilyl)methyl]benzyl methanesulfonates: Useful precursors for the generation of o -quinodimethanes
Shirakawa, Hidenori,Sano, Hiroshi
, p. 1788 - 1792 (2014/07/08)
2-[(Trimethylsilyl)methyl]benzyl methanesulfonates react with potassium fluoride in the presence of a catalytic amount of 18-crown-6 at room temperature to give o-quinodimethanes, which are trapped with electron-deficient olefins to afford [4+2] cycloadducts in good yields. Georg Thieme Verlag Stuttgart New York.
Palladium-catalyzed formal [4+2] cycloaddtion of o-xylylenes with olefins
Kuwano, Ryoichi,Shige, Takenori
, p. 3802 - 3803 (2008/02/03)
o-(Silylmethyl)benzylic carbonates reacted with various conjugated olefins in the presence of the palladium catalyst, which was generated in situ from Pd(η3-C3H5)Cp and 1,2-bis(diphenylphosphino)ethane (DPPE). The reaction
Potassium fluoride-induced 1,4-elimination of o-[(trimethylsilyl)methyl] benzyl acetates: A versatile generation of o-quinodimethanes
Kuwano, Ryoichi,Shige, Takenori
, p. 728 - 729 (2007/10/03)
o-Quinodimethane interemediate was generated from o-[(trimethylsilyl) methyl]benzyl acetate with potassium fluoride. The o-quinodimethane in hand reacted with electron-deficient olefins, affording [4+2] cycloadducts, tetrahydronaphthalenes. Copyright
