85807-87-0Relevant academic research and scientific papers
A new family of halogen-chelated hoveyda-grubbs-type metathesis catalysts
Barbasiewicz, Michal,Michalak, Michal,Grela, Karol
, p. 14237 - 14241,5 (2012)
Coordination, not insertion: New ruthenium benzylidenes with a chelating halogen atom were easily prepared and showed excellent stability and activity as metathesis catalysts (see figure). Structure-activity studies reveal that strength of the ruthenium-halogen interaction can be tuned across a wide range to set up a family of latent to active catalysts. Copyright
Complexes of ruthenum, method for their preparation, and their application in olefin metathesis reactions
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Page/Page column 23, (2015/07/15)
The present invention provides new ruthenium complexes of Formula (1), which contain a chelate ring created by a halogen atom X. The invention concerns also a method for the preparation of the new ruthenium complexes and their application in metathesis re
