858125-74-3Relevant articles and documents
Phosphine-Catalyzed Cascade Annulation of MBH Carbonates and Diazenes: Synthesis of Hexahydrocyclopenta[c]pyrazole Derivatives
Guo, Hongchao,Li, Hongxiang,Liu, Hao,Shi, Wangyu,Wang, Chang,Wang, Wei,Wu, Yongjun
, p. 5571 - 5575 (2021)
A phosphine-catalyzed cascade annulation of Morita-Baylis-Hillman (MBH) carbonates and diazenes was achieved, giving tetrahydropyrazole-fused heterocycles bearing two five-membered rings in moderate to excellent yields. The reaction underwent an unprecedented reaction mode of MBH carbonates, in which two molecules of MBH carbonates were fully merged into the ring system.
Process for producing hydroxyl group-containing vinyl compound
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Page/Page column 7; 8; 9, (2008/06/13)
A process for producing a hydroxyl group-containing vinyl compound, the process comprising: reacting an acrylate compound and an aldehyde-based compound in a presence of a tertiary amine compound and water in a reaction solution to produce a hydroxyl group-containing vinyl compound, wherein the reaction is performed by adding an inorganic salt of a Group 1 or 2 metal of Periodic Table to the reaction solution.