858132-44-2

Upstream product

• 167468-64-6 (2R)-2-(tert-butyldiphenylsiloxy)propanal 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 561038-05-9 (R)-2-(tert-butyldiphenylsilanyloxy)propionic acid methyl ester 
• 858132-43-1 ethyl (2E,4R)-4-([tert-butyl(diphenyl)silyl]oxy)-2-methylpent-2-enoate 

Downstream Products

• 858132-53-3 tert-Butyl-((E)-(R)-1,3-dimethyl-4-trityloxy-but-2-enyloxy)-diphenyl-silane 
• 858132-45-3 (2R,3E)-4-methyl-5-(trityloxy)pent-3-en-2-ol 
• 1026913-67-6 C₂₆H₂₅NO₂ 
• 858132-46-4 (1R,2E)-1,3-dimethyl-4-(trityloxy)but-2-en-1-yl carbamate 
• 858132-47-5 benzyl [(1R,2E)-1-methyl-1-[(trityloxy)methyl]but-2-en-1-yl] carbamate 
• 1354913-35-1 C₂₂H₂₈O₂Si 
• 1354913-25-9 (2S,4S,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-4-(tert-butoxycarbonylamino)-4-methylhept-5-enoate 
• 1354913-42-0 (2S,6R,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(carbamoyloxy)-4-methylhept-4-enoate 
• 1354913-40-8 (2S,6R,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-hydroxy-4-methylhept-4-enoate 
• 1354913-23-7 (2S,6R,E)-methyl 2-((benzyloxycarbonyl)(tert-butoxycarbonyl)amino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate 
• 1354913-15-7 (2S,6R,E)-methyl 2-(benzyloxycarbonylamino)-6-(tert-butyldiphenylsilyloxy)-4-methylhept-4-enoate 
• 1354913-37-3 (R,2Z,4E)-methyl 2-(benzyloxycarbonylamino)-6-(tert-butyl-diphenylsilyloxy)-4-methylhepta-2,4-dienoate 

Relevant academic research and scientific papers

Synthesis of manzacidin A and C: Efficient construction of quaternary carbon stereocenters bearing nitrogen substituents

An efficient synthetic method for stereoselective construction of asymmetric quaternary carbon stereocenters, bearing nitrogen in the form of Boc-protected allyl amines, has been developed. This methodology is employed in the synthesis of marine alkaloids

Synthesis of (+)-conagenin

An efficient total synthesis of (+)-conagenin was achieved. The right fragment of conagenin, α-methylserine containing a quaternary stereocenter attached to nitrogen, was synthesized using allyl cyanate-to-isocyanate rearrangement. The left fragment, 2,4-