858133-92-3Relevant academic research and scientific papers
Synthesis and ligand exchange reactions of P2Pd(II) and P 2Pt(II) salicylaldimates
Kerber, William D.,Nelsen, D. Luke,White, Peter S.,Gagne, Michel R.
, p. 1948 - 1951 (2005)
Reaction of (dppe)MCl2 (dppe = 1,2-bis(diphenylphosphino)ethane) with 2-(N-phenyliminomethyl)phenol leads to air-stable (dppe)M(N,O) chelates (M = Pd, 1a M = Pt, 1b). The N-4-methylphenyl derivative of la has been characterized by X-ray analysis. The N,O ligands are kinetically labile and exchange occurs in solution in the presence of other salicylaldimines. In the presence of anilines, a metal-mediated imine exchange process occurs. Hammett analysis reveals that the platinum complexes are sensitive to the electronics at N but not at O. Electron donating groups on the N-aryl ring stabilize the metal complex. The Royal Society of Chemistry 2005.
