85827-31-2

Upstream product

• 85827-30-1 (C₆H₅)(CH)4(CHO)Rh(C₅H₅) 

Downstream Products

• 85827-33-4 [Rh(C₆H₅COCH₂(CH)5C₆H₅)(C₅H₅)]⁽¹⁺⁾*PF₆^(1-)=[Rh(C₆H₅COCH₂(CH)5C₆H₅)(C₅H₅)]PF₆ 
• 85827-37-8 [Rh(C₆H₅COCH₂(CH)3CHCHC₆H₅)(C₅H₅)]⁽¹⁺⁾*BF₄^(1-)=[Rh(C₆H₅COCH₂(CH)3CHCHC₆H₅)(C₅H₅)]BF₄ 
• 85827-39-0 [RhBr(C₆H₅COCH₂(CH)3CHCHC₆H₅)(C₅H₅)] 

Relevant academic research and scientific papers

DIENE AND DIENYL COMPLEXES OF TRANSITION ELEMENTS. VI. THE PROTONATION OF TWO ISOMERIC (η5-CYCLOPENTADIENYL)(η4-1,7-DIPHENYLHEPTATRIEN-1-ONE)RHODIUM(I) COMPLEXES

Two isomeric complexes (η5-C5H5)> and (η5-C5H5)> have been prepared.The former reacts with HBF4 to give the salt 3-PhCOCH2(CH)3CH=CHPh>(η5-C5H5)>+BF4- in which the acyl CO group is coordinated to the metal.The latter, however, on treatment with HPF6, yields a η5-pentadienyl salt 5-PhCOCH2(CH)5Ph>(η5-C5H5)>+PF6-. 1H and some 13C NMR spectra are reported.