85829-28-3

Upstream product

• 645-45-4 hydrocinnamic acid chloride 
• 10290-42-3 1-diazo-4-phenyl-2-butanone 
• 85808-25-9 1-Chloro-4-phenyl-1-phenylsulfanyl-butan-2-one 
• 71-43-2 benzene 

Downstream Products

• 37985-17-4 1,4-diphenyl-2-butanone 

Relevant academic research and scientific papers

REGIOSPECIFIC SYNTHESIS OF α-(PHENYLTHIO)CYCLOALKENONES AND OF α-PHENYL-α-(PHENYLTHIO)KETONES VIA αα-ADDITION OF PHENYLSULPHENYL CHLORIDE TO α-DIAZOKETONES

Cyclic α-diazoketones react with phenylsulphenyl chloride at room temperature to furnish α-chloro-α-(phenylthio)cycloalkanones which undergo ready dehydrochlorination to α-(phenylthio)cycloalkenones when treated with triethylamine; acyclic, terminal α-diazoketones also furnish α-chloro-α-(phenylthio)adducts which are useful electrophiles in the synthesis of α-phenyl-α-(phenylthio)ketones.