85862-66-4Relevant academic research and scientific papers
Supramolecular columnar liquid crystals formed by hydrogen bonding between a clicked star-shaped s-triazine and benzoic acids
Feringán, Beatriz,Romero, Pilar,Serrano, José Luis,Giménez, Raquel,Sierra, Teresa
, p. 8859 - 8866 (2015)
A star-shaped tris(triazolyl)triazine is shown to establish hydrogen-bond interactions with polycatenar benzoic acids. The formation of hydrogen-bonded triazine/acid complexes has been demonstrated both in solution and in bulk by different techniques. The
Redox-active triazolium-derived ligands in nucleophilic fe-catalysis - Reactivity profile and development of a regioselective o-allylation
Klein, Johannes E. M. N.,Holzwarth, Michael S.,Hohloch, Stephan,Sarkar, Biprajit,Plietker, Bernd
supporting information, p. 6310 - 6316 (2013/10/21)
Triazolium-derived N-heterocyclic carbene (aNHC) ligands, which are readily accessible by deprotonation of the corresponding triazolium salts, proved to be versatile ligands in diverse allylic substitution reactions. The corresponding triazolium salts are formed from azides and alkynes through the application of 1,3-dipolar cycloaddition and N-alkylation reactions. The unique property of these ligands is to be zwitterionic in their liberated form and to act as strong redox-active σ-donor ligands. By virtue of these qualities, these ligands enable the development of an unprecedented Fe-catalyzed regioselective aryloxylation of allylic carbonates. Copyright
1,3-Dipolar cycloaddition of alkynes to azides. Construction of operationally functional metal responsive fluorophores
Schweinfurth, David,Hardcastle, Kenneth I.,Bunz, Uwe H. F.
, p. 2203 - 2205 (2008/12/23)
The copper catalyzed 1,3-dipolar cycloaddition of 4-butoxyphenylazide with 2-, 3- or 4-ethynylpyridine furnishes 1,4-diaryltriazoles, which display turn-on fluorescence upon addition of metal cations. The Royal Society of Chemistry.
