858803-73-3Relevant academic research and scientific papers
Spatially isolated palladium in porous organic polymers by direct knitting for versatile organic transformations
Wang, Xinbo,Min, Shixiong,Das, Swapan K.,Fan, Wei,Huang, Kuo-Wei,Lai, Zhiping
, p. 101 - 109 (2017/10/06)
We report here a direct knitting Method for preparation of highly robust, effective while air- and moisture-tolerant, and readily recyclable three-dimensional (3D) porous polymer-Pd network (PPPd) from the widely used Pd(PPh3)4. Electro-beam induced Pd atom crystallization was observed for the first time in organic polymer and revealed the ultrafine dispersion of palladium atoms. Challenging types of Suzuki-Miyaura couplings, reductive coupling of aryl halides and oxidative coupling of arylboronic acid were successively catalyzed by PPPd in aqueous media. Also catalytically selective C–H functionalization reactions were achieved with orders of magnitude more efficient than conventional Pd homogeneous catalysts. The strategy developed here provides a practical method for easy-to-make yet highly efficient heterogeneous catalysis.
Synthesis, spectral properties and photobehaviour of push-pull distyrylbenzene nitro-derivatives
Kika?,Carlotti,?kori?,?indler-Kulyk,Mazzucato,Spalletti
, p. 38 - 46 (2012/09/10)
Six novel asymmetric 2,5-distyryl-furan, 2,5-distyryl-thiophene and 2,6-distyrylpyridine derivatives, bearing an electron acceptor (p-nitro) group at one side and an electron donor (p-methoxy or p-dimethylamino) group at the other side, have been prepared. The experimental absorption properties have been measured and compared with the computed parameters. Theoretical and experimental results indicate that one conformational isomer (the compressed one) is largely prevalent in all compounds. The measured radiative and reactive relaxation properties of these donor/acceptor disubstituted compounds were also compared with those of the unsubstituted analogues previously investigated. The presence of the donor/acceptor groups leads to a significant increase of the charge transfer character of both the ground and the excited states and to strong red shifts of the absorption spectra, an effect that can be useful for potential applications in material science. The fluorescence/photoisomerization competition of the furan and thiophene derivatives was found to be rather similar to that of the unsubstituted analogues whereas significant changes were found for the pyridine derivatives where a drastic decrease of fluorescence, a sizable increase of photoisomerization and a predominance of radiationless deactivation to the ground state becomes operative.
