85915-66-8Relevant academic research and scientific papers
Synthesis of Isoflavanoid Oligomers Using a Pterocarpan as Inceptive Electrophile
Bezuidenhoudt, Barend C. B.,Brandt, Edward V.,Roux, David G.
, p. 2767 - 2778 (2007/10/02)
(3S)-2',7-Dihydroxy-4'-methoxyisoflavan serves as bifunctional nucleophile at C-5' and C-6, when condensed with the carbocation generated at C-11a of its (6aS,11aS)-3-hydroxy-9-methoxypterocarpan analogue under mild acid conditions or by photolysis, to fo
Direct Synthesis of the First Natural Bi-isoflavonoid
Brandt, Edward V.,Bezuidenhoudt, Barend C. B.,Roux, David G.
, p. 1409 - 1410 (2007/10/02)
The structure and stereochemistry of the first bi-isoflavonoid (3S,4S)-3,4-trans-2',7-dihydroxy-4'-methoxy-4-isoflavan (3) from Dalbergia nitidula are established by acid-induced condensation or photolysis of the appropriate pterocarpan and isoflavan precursors.
