85956-60-1

Basic information

• Product Name: trans-methyl 5-(trimethylsilyl)-3-cyclohexene-1-carboxylate
• Synonyms: trans-methyl 5-(trimethylsilyl)-3-cyclohexene-1-carboxylate
• CAS NO: 85956-60-1
• Molecular Weight: 212.364
• Mol File: 85956-60-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: trans-methyl 5-(trimethylsilyl)-3-cyclohexene-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: trans-methyl 5-(trimethylsilyl)-3-cyclohexene-1-carboxylate(85956-60-1)
• EPA Substance Registry System: trans-methyl 5-(trimethylsilyl)-3-cyclohexene-1-carboxylate(85956-60-1)

Safety Data

• Hazardous Substances Data: 85956-60-1(Hazardous Substances Data)

Upstream product

• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 60729-55-7 cis-methyl 5-acetoxycyclohex-3-enecarboxylate 
• 137488-64-3 (1S,5S)-5-(2,2,2-Trifluoro-acetoxy)-cyclohex-3-enecarboxylic acid methyl ester 
• 54911-89-6 cis-methyl 5-hydroxycyclohex-3-enecarboxylate 
• 65343-66-0 Tris(trimethylsilyl)aluminium 

Relevant articles and documents

Palladium-catalyzed allylic C-OH functionalization for efficient synthesis of functionalized allylsilanes

A new method is described for palladium-catalyzed allylic silylation using allylic alcohols and disilanes as precursors. The reactions proceed smoothly under mild and neutral conditions, and this method is suitable for synthesis of regioand stereodefined allylsilanes. The presented silylation reaction can be easily extended to include synthesis of allylboronates by change of the dimetallic reagent. The presented synthetic procedure offers a broad platform for the selective synthesis of functionalized allyl metal reagents, which are useful precursors in advanced organic chemistry and natural product synthesis.

Tris(trimethylsilyl)aluminum and Transition-Metal Catalysts. Silylation of Allyl Acetates

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