85972-71-0Relevant articles and documents
Regioselective Halogenation and Dimerization of Alkoxynaphathalenes with Alumina- or Kieselguhr-supported Copper(II) Halides
Suzuki, Yoshitada,Takeuchi, Kiyoshi,Kodomari, Mitsuo
, p. 426 - 427 (2007/10/03)
The reaction of 1-alkoxynaphathalenes 1 with alumina-supported copper(II) bromide or copper(II) chloride gave dimers, 4,4'-dialkoxy-1,1'-binaphthyls 3, as major products, and with Kieselguhr-supported copper(II) bromide afforded 1-bromo-4-alkoxynaphthalenes 2, while the reaction of 2-alkoxynaphathalenes 4 with alumina- or Kieselguhr-supported copper(II) bromide gave preferentially 1-bromo-2-alkoxynaphthalenes 5.
HALOGENATION REGIOSELECTIVE EN SERIE AROMATIQUE-II CHLORATION DES NAPHTOLS ET LEURS ETHERS A L'AIDE DE REACTIFS METTANT EN JEU DES INTERACTIONS DU TYPE DONNEUR-ACCEPTEUR
Guy, Alain,Lemaire, Marc,Guette, Jean-Paul
, p. 2347 - 2354 (2007/10/02)
The regispecific chlorination of naphtols by hexachlorocyclohexadienones as selective chlorinating reagents is described.The selectivity attained is better than that which we have obtained with phenol derivatives and confirms the importance of the donor-acceptor interaction between the reagent and the naphthol during the chlorination.