85972-73-2Relevant academic research and scientific papers
HYDROBORATION D'AMINES INSATUREES-IV; HYDROBORATION-ALKYLATION DE PROPARGYLAMINES PAR DES DIALKYLBORANES MIXTES
Torregrosa, J. L.,Baboulene, M.,Speziale, V.,Lattes, A.
, p. 3101 - 3106 (2007/10/02)
Hydroboration-alkylation of substituted or unsubstituted propargylamines with thexylalkylboranes rapidly gives good yields of ethylenic amines.A tendency towards rearranged products depends on the basicity of the starting acetylenic amines.Comparatively t
HYDROBORATION D'AMINES INSATUREES-II REGIO ET STEREOSELECTIVITE DE L'HYDROBORATION-ALKYLATION D'AMINES ACETYLENIQUES
Torregrosa, J. L.,Baboulene, M.,Speziale, V.,Lattes, A.
, p. 2355 - 2363 (2007/10/02)
The hydroboration reaction of acetylenic amines R1R2N-CH(R3)-CC-R4 was studied.We report the first results of a study of the reactivity of dialkylborane R2BH towards these amines which allow us to propose a new method for the synthesis of differently substituted β-ethylenic amines.The regioselectivity and the stereoselectivity of this reaction are examined and allow us to set out the possibility of a trans hydroboration.
