85982-97-4

Upstream product

• 3257-59-8 methyl 2,3-anhydro-4,6-O-benzylidene-α-D-gulopyranoside 
• 5674-01-1 2-methylallylmagnesium chloride 

Relevant academic research and scientific papers

REACTION OF 2,3-ANHYDRO-4,6-O-BENZYLIDENE-α-D-HEXOPYRANOSIDES WITH PROPENYLMAGNESIUM CHLORIDES. REGIOSELECTIVE CARBON CHAIN EXTENSION AT THE C-2 POSITION OF HEXAPYRANOSIDES

The reaction of 2-propenylmagnesium chlorides with methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside (1) or -gulopyranoside (6) exclusively afforded the corresponding 2-deoxy-2-C-(2-propenyl)-α-D-hexopyranosides (4b, 8a, and 8b).