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Pentacyclic Systems for Indole Alkaloids. Formation of the C11-C12 Bond. Two Synthesis of (+/-)-Aspidospermine
Gallagher, Timothy,Magnus, Philip,Huufman, John C.
, p. 4750 - 4757 (2007/10/02)
The tetracyclic amide 10 was converted through an intramolecular Pummerer reaction into the petacyclic amide11, having the basic framework of the Aspidosperma alkaloids.Application of this methodology to the synthesis of (+/-)-aspidosper
