860006-40-2Relevant academic research and scientific papers
Catalytic enantioselective indium-mediated allylation of hydrazones
Cook, Gregory R.,Kargbo, Robert,Maity, Bikash
, p. 2767 - 2770 (2007/10/03)
(Chemical Equation Presented) A facile and highly selective indium-mediated allylation of hydrazones utilizing BINOL ligands is described. Chiral (R)-3,3′-bistrifluoromethylBINOL afforded homoallylic amines in up to 97% ee with stoichiometric ligand. Employing only 10 mol % ligand afforded selectivity of up to 92% ee.
