860014-41-1

Upstream product

• 860014-47-7 (C₆H₅)4P⁽¹⁺⁾*Fe(CO)3(CN)2Br^(1-)=(P(C₆H₅)4)[Fe(CO)3(CN)2Br] 

Downstream Products

• 860014-46-6 PPh₄[Fe(CO)2(CN)2(1,3-propanedithiolate)Ni(S₂CN(CH₂)5] 
• 860014-44-4 PPh₄[Fe(CO)2(CN)2(1,3-propanedithiolate)Ni(S₂CNEt₂)] 

Relevant academic research and scientific papers

Dithiolato-bridged dinuclear iron-nickel complexes [Fe(CO) 2(CN)2(μ-SCH2CH2CH 2S)Ni(S2CNR2)]- modeling the active site of [NiFe] hydrogenase

[NiFe] hydrogenase, the enzyme of which catalyzes the reversible oxidation of molecular hydrogen to protons and electrons, contains a unique heterodinuclear thiolate-bridged Ni-Fe complex in which the iron center is coordinated by CO and CN. We have synthesized dithiolate-bridged Ni-Fe complexes bearing CO and CN ligands to model the active center of [NiFe] hydrogenase. The Ni-Fe complexes containing a [(CN)2(CO)2Fe(μ-S2)NiS2] framework are the closest yet structural models of [NiFe] hydrogenase. Copyright