86002-05-3Relevant academic research and scientific papers
Cu(OTf)2-catalyzed α-halogenation of ketones with 1,3-dichloro-5,5'-dimethylhydantoin and N-bromosuccinimide
Jagdale, Arun R.,Chouthaiwale, Pandurang V.,Sudalai, Arumugam
experimental part, p. 1424 - 1430 (2010/02/28)
Copper(II) triflate catalyses efficiently the α-halogentaion of aryl or alkyl ketones with l.3-diehloro-5.5'-dimethylhydantoin and N-bromosuccinimde to give the corresponding α,α-dichloroketones and α-bromoketones in high yield with excellent product selectivity.
DICHLOROMETHYL PHENYL SULFOXIDE: SYNTHETIC APPLICATIONS
Reutrakul, Vichai,Herunsalee, Kitivit
, p. 527 - 530 (2007/10/02)
Lithio dichloromethyl phenylsulfoxide reacts with aldehydes and alkyl halides to give the corresponding addition and alkylated products respectively.Pyrolysis of these compounds result in the formation of dichloroketones and terminal vinyl dichlorides.
