86014-18-8

Upstream product

• 3839-31-4 dimethyl(phenyl)silyl lithium 
• 96-10-6 diethylaluminium chloride 

Downstream Products

• 91076-26-5 Dimethyl-phenyl-((Z)-tridec-2-enyl)-silane 
• 91076-25-4 Dimethyl-phenyl-(1-vinyl-undecyl)-silane 
• 91076-24-3 2-dimethylphenylsilyl-1-tridecene 
• 91076-06-1 1-dimethylphenylsilyl-1-cyclononene 
• 91076-07-2 3-dimethylphenylsilyl-1-cyclononene 
• 68260-36-6 (E)-3,7-(dimethyl)-1-[dimethyl(phenyl)silyl]octa-2,6-diene 
• 87436-94-0 (1,5-Dimethyl-1-vinyl-hex-4-enyl)-dimethyl-phenyl-silane 
• 914785-34-5 dimethyl 5-(dimethylphenylsilyl)-3-pentene-1,1-dicarboxylate 
• 87437-05-6 ((E)-1-Butyl-pent-1-enyl)-dimethyl-phenyl-silane 
• 146513-23-7 dimethyl(cyclohex-2-en-1-yl)(phenyl)silane 

Relevant academic research and scientific papers

Preparation of 2-Alkenylsilanes and 2-Alkenylstannanes by the Reaction of 2-Alkenyl-1,1-cyclopropanedicarboxylate Esters with PhMe2SiAlEt2 and (Ph3Sn)2Zn. Generation of 2-Alkenyl-3-cyclopentene-1,1-dicarboxylates via Alkenyl-Substituted ?-Allylpalladium Complexes Derived from ...

Reaction of 2-vinyl-1,1-cyclopropanedicarboxylate with PhMe2SiAlEt2, PhMe2SiZnEt2Li, or (Ph3Sn)2Zn gave 1,7-homoconjugate addition products, 2-alkenylsilanes or 2-alkenylstannanes.In a similar fashion, 2-(1,3-butadienyl)-1,1-cyclopropanedicarboxylate provided the corresponding 1,9-homoconjugate adducts, dienylsilanes or dienylstannanes.The adducts were converted into ?-allylpalladium complexes by means of .Treatment of the alkenyl-substituted ?-allylpalladium complexes derived from dienylsilanes and with bases such as PPh3 or Na2CO3 gave 2-alkenyl-3-cyclopentene-1,1-dicarboxylates.In contrast, the reaction of the ?-allylpalladiums generated from 2-alkenylsilanes and with the bases resulted in the formation of original vinylcyclopropane derivatives.