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Triphenylphosphine(n-butylisocyanide)dicarbonyldibromoiron(II) is a complex organometallic compound with the chemical formula C26H26Br2FeNO3P. It consists of a central iron(II) atom coordinated to two bromine atoms, two carbonyl groups, a triphenylphosphine ligand, and a n-butylisocyanide ligand. triphenylphosphine(n-butylisocyanide)dicarbonyldibromoiron(II) is of interest in the field of organometallic chemistry and catalysis, as it exhibits unique electronic and steric properties that can influence its reactivity and potential applications in various chemical transformations. The presence of the triphenylphosphine and n-butylisocyanide ligands provides a sterically demanding environment around the iron center, which can affect the compound's coordination chemistry and its ability to interact with other molecules.

86015-64-7

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86015-64-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86015-64-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,0,1 and 5 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 86015-64:
(7*8)+(6*6)+(5*0)+(4*1)+(3*5)+(2*6)+(1*4)=127
127 % 10 = 7
So 86015-64-7 is a valid CAS Registry Number.

86015-64-7Downstream Products

86015-64-7Relevant academic research and scientific papers

Reductive Elimination and Substitution Reactions of Bis(triphenylphosphine)-dicarbonyldibromoiron(II)

Vancheesan, S.

, p. 54 - 55 (2007/10/02)

The title complex, Fe(CO)2(PPh3)2Br2(A) undergoes (i) substitution and (ii) reductive elimination.Substitution has been carried out with a variety of isocyanides, wherein a phosphine, a carbonyl or both the ligands are replaced by RNC.The extent and nature of the substitution varies with R, mol ratio of complex (A) to RNC and temperature.Reductive elimination has been carried out using Na/Hg as reducing agent in the presence of excess ligand L to get products of the type Fe(CO)2(PPh3)2L. ?-? character of L influence CO streaching frequencies.

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