Cas 86015-65-8,triphenylphosphine(phenylisocyanide)dicarbonyldibromoiron(II)

86015-65-8

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Basic information

Product Name: triphenylphosphine(phenylisocyanide)dicarbonyldibromoiron(II)
Synonyms:
CAS NO:86015-65-8
Molecular Formula:
Molecular Weight: 637.09
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: triphenylphosphine(phenylisocyanide)dicarbonyldibromoiron(II)(CAS DataBase Reference)
NIST Chemistry Reference: triphenylphosphine(phenylisocyanide)dicarbonyldibromoiron(II)(86015-65-8)
EPA Substance Registry System: triphenylphosphine(phenylisocyanide)dicarbonyldibromoiron(II)(86015-65-8)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 86015-65-8(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 86015-65-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,0,1 and 5 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 86015-65:
(7*8)+(6*6)+(5*0)+(4*1)+(3*5)+(2*6)+(1*5)=128
128 % 10 = 8
So 86015-65-8 is a valid CAS Registry Number.

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86015-65-8Relevant academic research and scientific papers

Reductive Elimination and Substitution Reactions of Bis(triphenylphosphine)-dicarbonyldibromoiron(II)

Vancheesan, S.

, p. 54 - 55 (2007/10/02)

The title complex, Fe(CO)2(PPh3)2Br2(A) undergoes (i) substitution and (ii) reductive elimination.Substitution has been carried out with a variety of isocyanides, wherein a phosphine, a carbonyl or both the ligands are replaced by RNC.The extent and nature of the substitution varies with R, mol ratio of complex (A) to RNC and temperature.Reductive elimination has been carried out using Na/Hg as reducing agent in the presence of excess ligand L to get products of the type Fe(CO)2(PPh3)2L. ?-? character of L influence CO streaching frequencies.

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