86029-78-9Relevant academic research and scientific papers
Chloro(phenylthio)methyltrimethylsilane: Preparation and some Synthetic Reactions
Yamamoto, Iwao,Okuda, Kazuhide,Nagai, Shigemasa,Motoyoshiya, Jiro,Gotoh, Haruo,Matsuzaki, Kei
, p. 435 - 438 (2007/10/02)
Reaction of the title compound (2) with lead thiocyanate gave phenylthio(trimethylsilyl)methyl isothiocyanate (3) which further reacted with aromatic aldehydes in the presence of fluoride ion to afford oxazoles in good yields.Compound (2) also reacted with silyl enol ethers to give β-silyl ketones which were capable of being converted into β-functionalized vinylsilanes.
THE PREPARATION β-KETOALDEHYDES
Ager, David J.
, p. 419 - 422 (2007/10/02)
β-Ketoaldehydes(7) were prepared by the addition of bromophenylthiotrimethylsilylmethane(6) to trimethylsilyl enol ethers(3) followed by a sila-Pummerer rearrangement and hydrolysis.
